This 1994 song by Scottish alternative rock band The Jesus & Mary Chain plays while Paris confronts Rory about the Jacob situation, lasting through Tristan’s fight with Dean.
The song is from the band’s album Stoned & Dethroned, and it is a duet between lead singer Jim Reid, and Hope Sandoval, who is the lead singer of American band Mazzy Star, which also featured in this episode. Sometimes Always peaked at #22 in the UK, but didn’t chart in the US.
The Annotated Gilmore Girls 